DENUDATION
The overall effect of the disintegration, wearing away, and removal of rock material is generally referred to as denudation, a term that implies a lowering of continental surfaces.
Denudation is accomplished by the interaction of three types of activities:
Weathering is the breaking down of rock into smaller components by atmospheric and biotic action agencies.
Mass wasting involves the relatively short-distance downslope movement of broken rock material under the direct influence of gravity.
Erosion consists of the removal, transportation, and eventual deposition of fragmented rock material over wider areas and sometimes to greater distances than is the case in mass wasting.
Weathering
Describes the combined action of all processes that cause rock to disintegrate physically and decompose chemically because of exposure near the Earth’s surface. There are two types of weathering which is:
Physical weathering where rocks are fractured and broken apart and
Chemical weathering where rock minerals are transformed from types that were stable when the rocks were formed to types that are now stable at the temperatures and pressures of the Earth’s surface.
Weathering produces regolith a surface layer of weathered rock particles that lies above solid, unaltered rock and also creates a number of distinctive landforms.
MECHANICAL WEATHERING
Mechanical weathering (or physical weathering) is the physical disintegration of rock material without any change in its chemical composition.
In essence, big rocks are mechanically weathered into little ones by various stresses that cause the rock to fracture into smaller and usually angular fragments. Most mechanical weathering occurs at or very near the surface, but under certain conditions it may occur at considerable depth.
Frost wedging: One of the most important physical weathering processes in cold climates is frost action. Unlike most liquids, water expands when it freezes. As water in the pore spaces of rocks freezes and thaws repeatedly, expansion can break even extremely hard rocks into smaller fragments. Even the strongest rocks cannot withstand frequent alternation of freezing and thawing. Water penetrates fractures in bedrock, if an opening in rock contains water, when the temperature falls below 0°C (32°F) ice forms, wedging its way downward. When the temperature rises above freezing, the ice melts and the water sinks farther into the slightly enlarged cavity. With renewed freezing, the wedging is repeated
Salt Wedging:
A similar physical weathering process occurs in dry climates. During long drought periods, ground water moves to the rock surface by capillary action a process in which the water’s surface tension causes it to be drawn through fine openings and passages in the rock. This water nearly always carries dissolved salts. When the water evaporates, as it commonly does, the salts are left behind as tiny crystals. With time, the crystals grow, prying apart the rock grain by grain, much in the fashion previously described for freezing water, although less. Salt-crystal growth occurs naturally in arid and semiarid regions, but in humid climates, rainfall dissolves salts and carries them downward to ground water.
Exfoliation or Unloading:
The most widely accepted explanation of massive exfoliation is that the rock cracks after an overlying weight has been removed, a process called unloading or pressure release .Rock that forms deep beneath the Earth’s surface is compressed by the rock above. As the upper rock is slowly worn away by erosion, the pressure is reduced, so the rock below expands slightly.
This expansion makes the rock crack in layers parallel to the surface, creating a sheeting structure. In massive rocks like granite or marble, thick, curved layers or shells of rock peel free from the parent mass below, producing an exfoliation dome.
Exfoliation occurs mainly in granite and related intrusive rocks, but under certain circumstances it is also seen in sandstone and other sedimentary strata. One of the most striking of all weathering processes is exfoliation, in which curved layers peel off bedrock.
Alternate wetting and drying.
Some clay minerals including smectite and vermiculite swell upon wetting and shrink when they dry out. Materials containing these clays, such as mudstone and shale, expand considerably on wetting, inducing micro crack formation, the widening of existing cracks, or the disintegration of the rock mass. Upon drying, the absorbed water of the expanded clays evaporates, and shrinkage cracks form. Alternate swelling and shrinking associated with wetting–drying cycles, in conjunction with the fatigue effect, leads to wet–dry weathering, or slaking, which physically disintegrates rocks.
Thermal weathering/thermal expansion/ thermoclasty:
Rocks have low thermal conductivities, which mean that they are not good at conducting heat away from their surfaces. When they are heated, the outer few millimeters become much hotter than the inner portion and the outsides expand more than the insides.
In addition, in rocks composed of crystals of different colours, the darker crystals warm up faster and cool down more slowly than the lighter crystals. All these thermal stresses may cause rock disintegration and the formation of rock flakes, shells, and huge sheets. Repeated heating and cooling produces a fatigue effect, which enhances the thermal weathering.
CHEMICAL WEATHERING.
Weathering involves a huge number of chemical reactions acting together upon many different types of rock under the full gamut of climatic conditions. Chemical reactions proceed more rapidly at warmer temperatures, so chemical weathering is most effective in the warm, moist climates of the equatorial, tropical, and subtropical zones six main chemical reactions are engaged in rock decomposition which are solution, hydration, oxidation and reduction, carbonation, and hydrolysis.
Carbonation
Occurs when carbon dioxide in water reacts with rock material to produce bicarbonate ions (HCO3–) and other ions that vary with the composition of the decomposing rock. Carbonation weathering is most effective on carbonate rocks (those containing CO3), particularly limestone, which is an abundant chemical precipitate sedimentary rock composed of calcium carbonate (CaCO3).
When water with sufficient carbon dioxide comes into contact with limestone, the chemical reaction creates calcium ions as well as bicarbonate ions. During carbonation, the calcium and carbonate in limestone detach from each other, thereby decomposing the limestone the process occurs as follows:
H2O + CO2 + CaCO3 = Ca2+ +2HCO3–.
Water carries away the ions of calcium and bicarbonate produced in the reaction. Similar reactions take place when other carbonate rocks undergo carbonation weathering. The process is dominant in humid climate due to role of water in the process.
Oxidation:
Oxidation means a combination of a mineral with oxygen to form oxides or hydroxides. When the oxygen dissolved in water comes into contact with certain rock minerals, the minerals undergo oxidation, in which the oxygen atoms combine with atoms of various metallic elements making up the minerals in the rock and form new products. The new substances are usually more voluminous, softer, and more easily removed than the original compounds. When iron-bearing minerals react with oxygen (in other words, become oxidized), iron oxide is produced:
4Fe + 3O2 S 2Fe2O3 Iron Oxygen Iron Oxide (Hematite)
This reaction, probably the most common oxidation in the lithosphere, is called rusting. Because iron and aluminum are very common in Earth’s crust, a reddish- brown color is seen in many rocks and soils, particularly in tropical areas because there oxidation is the most notable chemical weathering process. Rusting contributes significantly to weathering because oxides are usually softer and more easily removed than the original iron and aluminum compounds from which the oxides were formed.
Hydrolysis:
Is the chemical union of water with another substance to produce a new compound that is nearly always softer and weaker than the original. Igneous rocks are particularly susceptible to hydrolysis because their silicate minerals combine readily with water. Hydrolysis invariably increases the volume of the mineral, and this expansion can contribute to mechanical disintegration. In tropical areas, where water frequently percolates to considerable depth, hydrolysis often occurs far below the surface
Hydration:
Hydration is the chemical addition of water. Minerals take up water and expand; this expansion causes an increase in the volume of the material itself or rock. Calcium sulphate takes in water and turns to gypsum, which is more unstable than calcium sulphate. This process is reversible and long, continued repetition of this process causes fatigue in the rocks and may lead to their disintegration.
Solution
This process involves removal of solids in solution and depends upon solubility of a mineral in water or weak acids. On coming in contact with water many solids disintegrate and mix up as suspension in water.
Soluble rock forming minerals like nitrates, sulphates, and potassium are affected by this process. So, these minerals are easily leached out without leaving any residue in rainy climates and accumulate in dry regions.
The most soluble natural minerals are chlorides of the alkali metals: rock salt or halite (NaCl) and potash salt (KCl). These are found only in very arid climates. Gypsum (CaSO4.2H2O) is also fairly Soluble. Quartz has a very low solubility.
BIOLOGICAL WEATHERING
Biological weathering is contribution to or removal of minerals and ions from the weathering environment and physical changes due to growth or movement of organisms.
Burrowing and wedging by organisms like earthworms, termites, rodents help in exposing the new surfaces to chemical attack and assists in the penetration of moisture and air.
Human beings by disturbing vegetation, ploughing and cultivating soils, also help in mixing and creating new contacts between air, water and minerals in the earth materials.
Decaying plant and animal matter help in the production of humic, carbonic and other acids which enhance decay and solubility of some elements.
Plant roots exert a tremendous pressure on the earth materials mechanically break them apart.
References: geography an intergrated approach by David waugh, mc knight: principle of physical geography, labaratory mannual in physical geology